Let’s say you have a box full of particles, and each of those particles is independently in one of N states. Each state has a probability of occuring. Let us further suppose that none of these probabilities are the same - if so, then there is one state with the highest probability. If there are then properties E and V which are diagonal and have a 1-1 correspondence to each other amongst all the states, then the most common E and most common V definitely are related to each other by E=MV^2/2.
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Examine the Speed and Energy distributions of the ideal gas. The modal values of these two distributions do not correspond to each other via the E = MV^2/2 relation. Paradox?
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